Amination of Nitro-Substituted Heteroarenes by Nucleophilic Substitution of Hydrogen

Michael D. Mandler, Nina Suss, Antonio Ramirez, Christopher A. Farley, Darpandeep Aulakh, Yeheng Zhu, Sarah C. Traeger, Amy Sarjeant, Merrill L. Davies, Bruce A. Ellsworth, Alicia Regueiro-Ren

Organic Letters · 2022 · 10.1021/acs.orglett.2c03133

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★ 4.0 1 rating
5 : Major extension (new functional group)
4 : Minor extension (no new functional group) ×1
3 : Reproduced as published
2 : Reproduced with deviation
1 : Did not work
: Extension failed / Inconclusive

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Industry / CRO chemist
21 Aug 2026
★ 4 : Minor extension (no new functional group)

The reaction with the optimization substrate was reproduced in 2022 at ParazaPharma as easily as reported. Isolated yield was within +/- 5% on a duplicate.
2 analogues, which were not reported in the publication worked within the same isolated yield range.